1 Section of Chemical Engineering, The Faculty of Engineering and Science, Aalborg University, VBN2 CIChem Research Group (Colloid and Interface Chemistry), The Faculty of Engineering and Science, Aalborg University, VBN3 Esbjerg Institute of Technology, Aalborg University, The Faculty of Engineering and Science (ENG), Aalborg University, VBN4 SCF-Technologies A/S5 JJ X-Ray Systems ApS
A novel method for producing crystalline nanosized metal oxides by a Supercritical Seed Enhanced Crystallization (SSEC) Process has been developed. The process is a modified sol-gel process taking place at temperatures as low as 95 ºC with supercritical CO2 as solvent and polypropylene as seeding material. The nanocrystalline product is obtained without having to resort to costly post-reaction processing and the product is obtained directly after the SSEC process. TiO2 powders produced by the SSEC process were shown to have a crystallinity of 60 % and a crystal size of 7.3 ± 2.6 nm. The crystallinity can be controlled by changing the heating rate of the initial formation of the nanoparticles and the morphology can be altered by changing the process time.
Industrial and Engineering Chemistry Research, 2006, Vol 45, Issue 10, p. 3348-3353