Mortensen, Peter Mølgaard1; Gardini, Diego2; de Carvalho, Hudson W. P.6; Damsgaard, Christian Danvad2; Grunwaldt, Jan-Dierk6; Jensen, Peter Arendt1; Wagner, Jakob Birkedal2; Jensen, Anker Degn1
1 Department of Chemical and Biochemical Engineering, Technical University of Denmark2 Center for Electron Nanoscopy, Technical University of Denmark3 Department of Physics, Technical University of Denmark4 Experimental Surface and Nanomaterials Physics, Department of Physics, Technical University of Denmark5 CHEC Research Centre, Department of Chemical and Biochemical Engineering, Technical University of Denmark6 Karlsruhe Institute of Technology
carbon deposition and effects of sulfur, potassium, and chlorine in the feed
The long term stability and resistance toward carbon deposition, sulfur, chlorine, and potassium of Ni/ZrO2 as a catalyst for the hydrodeoxygenation (HDO) of guaiacol in 1-octanol (as a model compound system for bio-oil) has been investigated at 250 degrees C and 100 bar in a trickle bed reactor setup. Without impurities in the feed good stability of the Ni/ZrO2 catalyst could be achieved over more than 100 h of operation, particularly for a sample prepared with small Ni particles, which minimized carbon deposition. Exposing the catalyst to 0.05 wt% sulfur in the feed resulted in rapid deactivation with complete loss of activity due to the formation of nickel sulfide. Exposing Ni/ZrO2 to chlorine-containing compounds (at a concentration of 0.05 wt% Cl) on-stream led to a steady decrease in activity over 40 h of exposure. Removal of the chlorine species from the feed led to the regaining of activity. Analysis of the spent catalyst revealed that the adsorption of chlorine on the catalyst was completely reversible, but chlorine had caused sintering of nickel particles. In two experiments, potassium, as either KCl or KNO3, was impregnated on the catalyst prior to testing. In both cases deactivation was persistent over more than 20 h of testing and severely decreased the deoxygenation activity while the hydrogenation of guaiacol was unaffected. Overall, sulfur was found to be the worst poison, followed by potassium and then chlorine. Thus, removal/limitation of these species from bio-oil is a requirement before long term operation can be achieved with this catalyst.
Catalysis Science and Technology, 2014, Vol 4, Issue 10, p. 3672-3686