Accurate prediction of saturated hydraulic conductivity (Ksat) is essential for the development of better distributed hydrological models and area-differentiated risk assessment of chemical leaching. The saturated hydraulic conductivity is often estimated from basic soil properties such as particle size distribution or, more recently, soil-air permeability. However, similar links to soil gas diffusivity (Dp/Do) have not been fully explored even though gas diffusivity is a direct measure of connectivity and tortuosity of the soil pore network. Based on measurements for a coarse sandy soil, potential relationships between Ksat and Dp/Do were investigated. A total of 84 undisturbed soil cores were extracted from the topsoil of a field site, and Dp/Do and Ksat were measured in the laboratory. Water-induced and solids-induced tortuosity factors were obtained by applying a two-parameter Dp/Do model to measured data, and subsequently linked to the cementation exponent of the wellestablished Revil and Cathles predictive model for saturated hydraulic conductivity. Furthermore, a two-parameter model, analogue to the Kozeny-Carman equation, was developed for the Ksat - Dp/Do relationships. All 44 analyses implied strong and fundamental relationships between Ksat and Dp/Do.