1 Department of Photonics Engineering, Technical University of Denmark2 Nanophotonic Devices, Department of Photonics Engineering, Technical University of Denmark3 Center for Electron Nanoscopy, Technical University of Denmark4 Programmable Phase Optics, Department of Photonics Engineering, Technical University of Denmark5 Department of Micro- and Nanotechnology, Technical University of Denmark6 Nanointegration, Department of Micro- and Nanotechnology, Technical University of Denmark7 Amphiphilic Polymers in Biological Sensing, Department of Micro- and Nanotechnology, Technical University of Denmark8 Center for Nanostructured Graphene, Center, Technical University of Denmark
The development of epitaxial technology for the fabrication of quantum dot (QD) gain material operating in the 1.55 μm wavelength range is a key requirement for the evolvement of telecommunication. High performance QD material demonstrated on GaAs only covers the wavelength region 1-1.35 μm. In order to extract the QD benefits for the longer telecommunication wavelength range the technology of QD fabrication should be developed for InP based materials. In our work, we take advantage of both QD fabrication methods Stranski-Krastanow (SK) and selective area growth (SAG) employing block copolymer lithography. Due to the lower lattice mismatch of InAs/InP compared to InAs/GaAs, InP based QDs have a larger diameter and are shallower compared to GaAs based dots. This shape causes low carrier localization and small energy level separation which leads to a high threshold current, high temperature dependence, and low laser quantum efficiency. Here, we demonstrate that with tailored growth conditions, which suppress surface migration of adatoms during the SK QD formation, much smaller base diameter (13.6nm versus 23nm) and an improved aspect ratio are achieved. In order to gain advantage of non-strain dependent QD formation, we have developed SAG, for which the growth occurs only in the nano-openings of a mask covering the wafer surface. In this case, a wide range of QD composition can be chosen. This method yields high purity material and provides significant freedom for reducing the aspect ratio of QDs with the possibility to approach an ideal QD shape.
Proceedings of Spie, the International Society for Optical Engineering, 2014, Vol 8996
Main Research Area:
SPIE Photonics West : Quantum Dots and Nanostructures: Synthesis, Characterization, and Modeling XI, 2014