1 Department of Chemical and Biochemical Engineering, Technical University of Denmark2 CHEC Research Centre, Department of Chemical and Biochemical Engineering, Technical University of Denmark3 The Danish Polymer Centre, Department of Chemical and Biochemical Engineering, Technical University of Denmark4 DONG Energy A/S5 Centre for oil and gas – DTU, Center, Technical University of Denmark
The properties of slurries made of pyrolysis oil mixed with wood, char or ground char were investigated with respect to phase transitions, rheological properties, elemental compositions, and energy density. Also the pumping properties of the slurries were investigated at temperatures of 25, 40 and 60 C and solid loadings from 0 to 20 wt%. The phase transitions of the wood slurry samples were observed at lower solid loadings compared to the char slurry samples. The apparent viscosity of the slurry samples was found to be considerably impacted by solid loading (0e20 wt%) and temperature (25e60 C), especially in the phase transition region. The slurry viscosities with 20 wt% char loading, 20 wt% ground char loading and 15 wt% wood loading (at a shear rate of 100 s1) are 0.7, 1.0 and 1.7 Pa.s, respectively at 60 C and these values increases 1.2e1.4 times at 40 C and 3e4 times at 25 C. The wood, char and ground char slurry samples with 5e20 wt% solid loading obtain a volumetric energy density of 21e23 GJ/m3. The slurry sample with 20 wt% ground char having a d80 of 118 mm was pumped successfully into a pressurized chamber (0e6 bar) while plugging appeared when the slurry samples with 15 wt% char having a d80 of 276 mm was pumped into the pressurized chamber.
Biomass and Bioenergy, 2014, Vol 61, p. 227-235
Bioslurry; Pressurized gasification; Biomass fast pyrolysis; Slurry pumping; Biomass energy densification