Indium-doped tin oxide free electrochromic devices are prepared by coating electrochromic polymers onto polyethylene terephthalate substrates encompassing two different silver grids as electrodes. One design comprises a fl exoprinted highly conductive silver grid electrode, yielding electrochromic devices with a response time of 2 s for an optical contrast of 27%. The other design utilizes an embedded silver grid electrode whereupon response times of 0.5 s for a 30% optical contrast are realized when oxidizing the device. A commercially available conductive poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate acid) formulation (PEDOT:PSS) is coated onto the silver grids as a charge balancing polymer, and is in this setting found to be superior to a polypyrrole previously employed in electrochromic devices. In addition, the PEDOT:PSS layer increases the conductivity in the hexagonal grid structure.
Advanced Functional Materials, 2014, Vol 24, p. 1228-1233