Hansen, Per Lunnemann3; Rabouw, Freddy T.4; van Dijk-Moes, Relinde J. A.4; Pietra, Francesca4; Vanmaekelbergh, Daniël4; Koenderink, A. Femius5
1 Department of Photonics Engineering, Technical University of Denmark2 Nanophotonics Theory and Signal Processing, Department of Photonics Engineering, Technical University of Denmark3 Nanophotonics, Department of Photonics Engineering, Technical University of Denmark4 Debye Institute for Nanomaterials Science5 FOM Institute for Atomic and Molecular Physics
We demonstrate that a simple silver coated ball lens can be used to accurately measure the entire distribution of radiative transition rates of quantum dot nanocrystals. This simple and cost-effective implementation of Drexhage’s method that uses nanometer-controlled optical mode density variations near a mirror, not only allows an extraction of calibrated ensemble-averaged rates, but for the first time also to quantify the full inhomogeneous dispersion of radiative and non radiative decay rates across thousands of nanocrystals. We apply the technique to novel ultrastable CdSe/CdS dot-in-rod emitters. The emitters are of large current interest due to their improved stability and reduced blinking. We retrieve a room-temperature ensemble average quantum efficiency of 0.87 ± 0.08 at a mean lifetime around 20 ns. We confirm a log-normal distribution of decay rates as often assumed in literature, and we show that the rate distribution-width, that amounts to about 30% of the mean decay rate, is strongly dependent on the local density of optical states.
A C S Nano, 2013, Vol 7, Issue 7
Quantum dots; Nanorods; Quantum rods; Quantum efficiency; Drexhage; Optical density of states; Decay-rate distribution