1 Department of Energy Conversion and Storage, Technical University of Denmark2 Ceramic Engineering & Science, Department of Energy Conversion and Storage, Technical University of Denmark3 Mixed Conductors, Department of Energy Conversion and Storage, Technical University of Denmark4 Banaras Hindu University5 Risø National Laboratory for Sustainable Energy, Technical University of Denmark6 Banaras Hindu University
The sintering of asymmetric CGO bi-layers (thin dense membrane on a porous support; Ce0.9Gd0.1O1.95-delta = CGO) with Co3O4 as sintering additive has been optimized by combination of two in situ techniques. Optical dilatometry revealed that bi-layer shape and microstructure are dramatically changing in a narrow temperature range of less than 100 degrees C. Below 1030 degrees C, a higher densification rate in the dense membrane layer than in the porous support leads to concave shape, whereas the densification rate of the support is dominant above 1030 degrees C, leading to convex shape. A fiat bi-layer could be prepared at 1030 degrees C, when shrinkage rates were similar. In situ van der Pauw measurements on tape cast layers during sintering allowed following the conductivity during sintering. A strong increase in conductivity and in activation energy E-a for conduction was observed between 900 and 1030 degrees C indicating an activation of the reactive sintering process and phase transformation of cobalt oxide. (C) 2012 Elsevier Ltd. All rights reserved.
Journal of the European Ceramic Society, 2013, Vol 33, Issue 3, p. 549-556
Doped ceria; Multi-layer sintering; Sintering aid; Optical dilatometry; van der Pauw