Measurements of diffusive and convective gas transport parameters can be used to describe soil functional architecture and reveal key factors for soil structure development. Undisturbed 100-cm(3) soil samples were sampled at the Long-term Research on Agricultural Systems experiment located at the University of California, Davis. The 18 plots used in this study represented fairly wide ranges in organic carbon (0. 0072-0.0153 kg kg(-1)) and clay (0.30-0.44 kg kg(-1)). Soil-air permeability, k(a), and soil-gas diffusivity, D-P/D-0, were determined at field-moist conditions (fin) and, subsequently, after saturation and drainage to - 100 cm of matric potential (pF2). Gas diffusivity in intact samples at fm conditions exhibited a general, linear relationship with air-filled porosity (epsilon), independent of soil texture and treatment. Comparing intact and repacked samples drained to pF2, repacked soil displayed markedly lower D-P/D-0 values at similar air-filled porosity, illustrating soil structure effects on D-P/D-0. The Currie tortuosity-connectivity parameter, X=Log(D-P/D-0)/Log(epsilon), decreased with increasing bulk density in the intact samples at both moisture conditions, suggesting less tortuous and well-connected pathways for gas diffusion at higher bulk density. Pore organization, PO = k(a) / epsilon, showed a treatment effect with typically higher values for the organic plots, implying that an improved possibility for formation of organomineral soil aggregates resulted in better-connected macropore networks. Fitting a linear model to D-P/D-0 versus epsilon measurements revealed different slopes at the two moisture conditions, suggesting short-term nonsingularity (hysteretic) effects after rewetting and drainage.