Eriksen, Kim Michael1; Fehrmann, Rasmus1; Hatem, Gerard2; Gaune-Escard, Marcelle2; Lapina, Olga B.3; Mastikhin, Vladimir M.3
1 Department of Chemistry, Technical University of Denmark2 Université de Provence3 Boreskov Institute of Catalysis
The phase diagram of the catalytically important K2S2O7-KHSO4 molten salt solvent system has been investigated by electrochemical, thermal and spectroscopic methods.It is of the simple eutectic type with a temperature of fusion of 205C for the eutectic composition, X(KHSO4)= 0.94. The conductivities of the solid and molten K2S2O7-KHSO4 system were measured at 13 different compositions in the whole composition range, X(KHSO4)= 0-1. The conductivity of the molten mixtures were fitted to polynomia of the second degree.The results indicated delocalization of the conducting ions compared to the pure molten components.
J. Phys. Chem, 1996, Vol 100, Issue 25, p. 10771-10778