1 Department of Chemistry, Technical University of Denmark2 University of Reading
A series of fourteen novel pyrrole monomers substituted at the 3-position with aliphatic and aromatic crown-ether moieties have been synthesised in good yield and characterised extensively. Several of those compounds were electropolymerised successfully in acetonitrile, using both potentiostatic and galvanostatic modes and the electrochemical properties of those systems were studied via cycling voltammetry in aqueous and organic media. Novel crown-ether substituted polypyrrole derivatives revealed reversible redox couples in LiClO4/CH3CN (0.1 M). The morphology of these novel crown-ether substituted polypyrrole derivatives was characterised by Scanning Electron Microscopy (SEM). These polymers exhibited an open porous structure and half the charge was required when compared to polypyrrole to afford films of equal thickness. The mass change during polymerisation was followed by Electrochemical Quartz Crystal Microbalance measurement (EQCM), and the rate of polymer growth was found to be non-linear when compared to polypyrrole.
Reactive and Functional Polymers, 2006, Vol 66, Issue 1, p. 201-208