The formation of deposits during suspension-firing of wood at Avedøre Power Plant unit 2 (AVV2) was studied by using an advanced deposit probe system. The tests were conducted both with and without coal ash addition, and at two different locations with flue gas temperatures of 1250-1300 oC and 750-800 oC respectively. The deposit formation process was studied quantitatively though the mass uptake data from the load-cell of the probe, while camera pictures were used to qualitatively verify the obtained mass uptake data and to explain the deposit buildup/shedding mechanisms. The collected deposits along with the fly ash and bottom ash from the plant were characterized extensively by SEM-EDS, ICP-OES/IC and XRD. Based on the results from the present work, the deposit formation and shedding mechanisms under different operational conditions were proposed and discussed. The influence of coal ash addition on deposit formation during wood suspension-firing at AVV2 was evaluated. It was revealed that the addition of coal fly ash could significantly influence the ash deposition/shedding behaviors and the deposit properties. The effect was evident at both measurement locations. At the location with a high flue gas temperature of 1250-1300 oC, although the addition of coal fly ash increased the differential deposit formation rate (DDF-rate) and the ash deposition propensity, the deposit removal frequency were considerably increased and the major shedding mechanism was changed from soot-blowing induced shedding to natural shedding. This implied that the deposits at high temperatures were more easily removable when coal ash was added. Besides, the amount of K2SO4 in the high-temperature deposits was considerably reduced when coal ash was added, which was probably favorable in order to minimize corrosion. At the location with a low flue gas temperature of 750-800 oC, the addition of coal fly ash reduced the ash deposition propensity and caused the formed deposits being easily removable. Moreover, the KCl and KOH/K2CO3 found in the low-temperature deposits without coal ash addition disappeared when coal ash was added, which was also favorable from a corrosion point of view.
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Technical University of Denmark, Department of Chemical Engineering, 2012