1 Department of Chemical and Biochemical Engineering, Technical University of Denmark2 Center for Energy Resources Engineering, Center, Technical University of Denmark
The extended universal quasichemical (UNIQUAC) model is a thermodynamic model for solutions containing electrolytes and non-electrolytes. The model is a gibbs excess function consisting of a Debye-Hückel term and a standard UNIQUAC term. The model only requires binary, ion specific interaction parameters. A unique choice of standard states makes the model able to reproduce solid-liquid, vapor-liquid, and liquid-liquid phase equilibria as well as thermal properties of electrolyte solutions using one set of parameters.
Journal of Pure and Applied Chemistry, 2005, Vol 77, Issue 3, p. 531-542