1 Department of Energy Conversion and Storage, Technical University of Denmark2 Mixed Conductors, Department of Energy Conversion and Storage, Technical University of Denmark3 Risø National Laboratory for Sustainable Energy, Technical University of Denmark
The effect of single layer La0.85Sr0.15MnO3−δ (LSM) coatings on high temperature oxidation behaviour of four commercial chromia-forming steels, Crofer 22 APU, Crofer 22 H, E-Brite and AL 29-4C, is studied. The samples were oxidized for 140–1000 h at 1123 K in flowing simulated ambient air (air + 1% H2O) and oxygen and corrosion kinetics monitored by mass increase of the materials over time. The oxide scale microstructure and chemical composition are investigated by scanning electron microscopy/energy-dispersive spectroscopy. The kinetic data obey a parabolic rate law. The results show that the LSM coating acts as an oxygen transport barrier that can significantly reduce the corrosion rate.
International Journal of Hydrogen Energy, 2012, Vol 37, Issue 9, p. 8087-8094
Oxide scale growth; High temperature corrosion; Parabolic rate law; Ionic diffusion
Main Research Area:
7th Petite Workshop on the Defect Chemical Nature of Energy Materials, 2012