Pérez, J.2; García, L.2; Kessler, M.2; Nolsøe, Kim1; Pérez, E. E.2; Serrano, J.2; Martínez, J. F.2; Carrascosa, R. L.2
1 Department of Informatics and Mathematical Modeling, Technical University of Denmark2 unknown
A statistical classification of the solid state conformation in the title complexes using data retrieved from the Cambridge Structural Database (CSD) has been made. Phosphate and phosphinate complexes show a chair conformation preferably. In phosphonate complexes, the most frequent conformations are found to be boat–chair, chair and boat–boat; in all the boat–chair cases, the phosphorus atoms appear connected by a bridging carbon atom.
Inorganica Chimica Acta, 2005, Vol 358, Issue 7, p. 2432-2436