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Static properties of polystyrene in semidilute solutions: A comparison of Monte Carlo simulation and small-angle neutron scattering results

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Authors:
  • Pedersen, J.S. ;
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    Risø National Laboratory for Sustainable Energy, Technical University of Denmark
  • Schurtenberger, P.
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    unknown
DOI:
10.1209/epl/i1999-00219-7
Abstract:
Monte Carlo simulations have been performed on a meso-scale polymer model for semiflexible chains and effective polymer-polymer interactions. Simulations were made for different chain lengths at dilute and semidilute concentrations, The correlation length and osmotic compressibility have been determined for the simulations as well as experimentally for polystyrene in d-toluene by small-angle neutron scattering (SANS), and excellent agreement is found. Interpolations of the MC scattering functions fit the SANS data in the full measured range of scattering vectors, demonstrating agreement almost down to atomic level.
Type:
Journal article
Language:
English
Published in:
Europhysics Letters, 1999, Vol 45, Issue 6, p. 666-672
Keywords:
Nye funktionelle materialer
Main Research Area:
Science/technology
Publication Status:
Published
Review type:
Undetermined
Submission year:
1999
Scientific Level:
Scientific
ID:
2156182982

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